<p>A new oleanane-type triterpene, 11<i>α</i>-hydroperoxyolean-12-en-3-one, together with two known oleanane-type triterpenes, oleanolic acid and 3<i>β</i>-acetyloxyolean-12-en-28-oic acid, were isolated from the fruits of <i>Morinda citrifolia</i>. Their structures were established by analysis of spectroscopic data, including 1D and 2D NMR (<sup>1</sup>H, <sup>13</sup>C, COSY, HMQC, HMBC, and NOESY) and HR-ESI-MS, as well as by comparison with the spectral data of known analogs.</p>

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A New Oleanane Triterpenoid from the Fruits of Morinda citrifolia

  • Chien-Hung Kuo,
  • Shu-Ju Li,
  • Yu-Kuang H. Chen,
  • Chi-I Chang

摘要

A new oleanane-type triterpene, 11α-hydroperoxyolean-12-en-3-one, together with two known oleanane-type triterpenes, oleanolic acid and 3β-acetyloxyolean-12-en-28-oic acid, were isolated from the fruits of Morinda citrifolia. Their structures were established by analysis of spectroscopic data, including 1D and 2D NMR (1H, 13C, COSY, HMQC, HMBC, and NOESY) and HR-ESI-MS, as well as by comparison with the spectral data of known analogs.