<p>A new phyllocladane-type diterpenoid, 3-oxophyllocladane-16α,18-diol (<b>1</b>) and one known phyllocladane-type diterpenoid, 3-oxophyllocladan-16α-ol (<b>2</b>) were isolated from the bark of <i>Cryptomeria japonica</i>. Their structures were elucidated on the basis of spectroscopic analysis including 1D and 2D NMR (<sup>1</sup>H, <sup>13</sup>C, COSY, HMQC, HMBC, and NOESY) and HR-EI-MS and comparison of NMR data with those of known analogs.</p>

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Phyllocladane Diterpenoids from the Bark of Cryptomeria japonica

  • Chi-I Chang,
  • Cheng-Chi Chen,
  • Yueh-Hsiung Kuo

摘要

A new phyllocladane-type diterpenoid, 3-oxophyllocladane-16α,18-diol (1) and one known phyllocladane-type diterpenoid, 3-oxophyllocladan-16α-ol (2) were isolated from the bark of Cryptomeria japonica. Their structures were elucidated on the basis of spectroscopic analysis including 1D and 2D NMR (1H, 13C, COSY, HMQC, HMBC, and NOESY) and HR-EI-MS and comparison of NMR data with those of known analogs.