<p>The herb of <i>Nonea rossica</i> Steven (Boraginaceae) contained 23 compounds, including new acetates of astragalin and trifolin (<b>1–5</b>). UV and NMR spectroscopy and mass spectrometry found that the new flavonoids were kaempferol 3-<i>O</i>-(3′′-<i>O</i>-acetyl)-<i>β</i>-D-glucopyranoside (noneaside B, <b>1</b>), kaempferol 3-<i>O</i>-(3′′-<i>O</i>-acetyl)-<i>β</i>-D-galactopyranoside (noneaside C, <b>2</b>), kaempferol 3-<i>O</i>-(4′′-O-acetyl)-<i>β</i>-Dglucopyranoside (noneaside D, <b>3</b>), kaempferol 3-<i>O</i>-(4′′-<i>O</i>-acetyl)-<i>β</i>-D-galactopyranoside (noneaside E, <b>4</b>), and kaempferol 3-<i>O</i>-(3′′,6′′-di-<i>O</i>-acetyl)-<i>β</i>-D-galactopyranoside (noneaside F, <b>5</b>).</p>

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New Acetates of Astragalin and Trifolin from Nonea rossica

  • D. N. Olennikov,
  • M. E. Kartashova,
  • V. V. Velichko,
  • D. S. Kruglov,
  • N. K. Chirikova

摘要

The herb of Nonea rossica Steven (Boraginaceae) contained 23 compounds, including new acetates of astragalin and trifolin (1–5). UV and NMR spectroscopy and mass spectrometry found that the new flavonoids were kaempferol 3-O-(3′′-O-acetyl)-β-D-glucopyranoside (noneaside B, 1), kaempferol 3-O-(3′′-O-acetyl)-β-D-galactopyranoside (noneaside C, 2), kaempferol 3-O-(4′′-O-acetyl)-β-Dglucopyranoside (noneaside D, 3), kaempferol 3-O-(4′′-O-acetyl)-β-D-galactopyranoside (noneaside E, 4), and kaempferol 3-O-(3′′,6′′-di-O-acetyl)-β-D-galactopyranoside (noneaside F, 5).