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<p></p><p><InlineMediaObject> <ImageObject Color="Color" FileRef="MediaObjects/10593_2025_3397_Figc_HTML.png" Format="PNG" Height="213" Rendition="HTML" Resolution="300" Type="LinedrawHalftone" Width="179" /> </InlineMediaObject>This microreview summarizes the advances in C(sp<sup>2</sup>)–H bond carbonylation reactions with CO<sub>2</sub> catalyzed by transition metals over the past seven years (2018–2024). The reviewed reactions yield two kinds of heterocyclic compounds (lactones and lactams), which are frequently found in chemicals, pharmaceuticals, natural goods, and economically valuable raw materials. This review is structured based on the transition metal catalysts employed in the reactions highlighting the advantages, disadvantages, and products of each reaction category.</p><p></p>

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Transition-metal-catalyzed carbonylation of C(sp2)–H bonds with CO2 to generate heterocyclic compounds (microreview)

  • 期刊论文

  • 发表日期：

    2025年2月1日

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  • Yuting Liu,
  • Zhen Zhang

摘要

This microreview summarizes the advances in C(sp2)–H bond carbonylation reactions with CO2 catalyzed by transition metals over the past seven years (2018–2024). The reviewed reactions yield two kinds of heterocyclic compounds (lactones and lactams), which are frequently found in chemicals, pharmaceuticals, natural goods, and economically valuable raw materials. This review is structured based on the transition metal catalysts employed in the reactions highlighting the advantages, disadvantages, and products of each reaction category.