<p>We examine the thermocatalytic conversion of an individual gaseous hydrocarbon, namely, propane, serving as a model of an associated petroleum gas component in the presence of a modified metal complex catalytic system derived from inorganic compounds. The thermocatalytic conversion of propane was carried out using a catalytic system consisting of a Y‑type zeolite support in the Na form, whose surface was modified by a complex salt derived from ferric chloride and potassium chloride. This catalytic system had a highly‑developed surface and selective catalytic activity for the preparation of aromatic compounds. This zeolite‑containing catalytic system proved effective for the conversion of propane at 500‑600°C with hourly space velocity 1‑2 h<sup>‑1</sup> to give petrochemical products with the predominance of liquid hydrocarbons, namely, C<sub>6</sub>–C<sub>8</sub> aromatic compounds containing various spatial isomers.</p>

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Thermocatalytic Conversion of a Gaseous Hydrocarbon Feedstock in the Presence of Catalytic Systems Derived from Inorganic Compounds

  • A. D. Badikova,
  • S. R. Sakhibgareev,
  • M. A. Tsadkin,
  • T. R. Vakhitov

摘要

We examine the thermocatalytic conversion of an individual gaseous hydrocarbon, namely, propane, serving as a model of an associated petroleum gas component in the presence of a modified metal complex catalytic system derived from inorganic compounds. The thermocatalytic conversion of propane was carried out using a catalytic system consisting of a Y‑type zeolite support in the Na form, whose surface was modified by a complex salt derived from ferric chloride and potassium chloride. This catalytic system had a highly‑developed surface and selective catalytic activity for the preparation of aromatic compounds. This zeolite‑containing catalytic system proved effective for the conversion of propane at 500‑600°C with hourly space velocity 1‑2 h‑1 to give petrochemical products with the predominance of liquid hydrocarbons, namely, C6–C8 aromatic compounds containing various spatial isomers.