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The Activity of Trimetallic Catalysts in the Hydrotreating of a Mixed Diesel Fraction

  • I. A. Arkhipova,
  • E. G. Petrova,
  • V. V. Fadeev,
  • S. V. Zaglyadova,
  • A. Kh. Kuptsov,
  • E. A. Chernysheva

摘要

A study was carried out on the effect of the nature of the support, composition of the active phase, and heat treatment conditions on the activity of trimetallic Ni‑Co‑Mo catalysts in the hydrotreating of a mixed diesel fraction. Temperature‑programmed desorption was used to show the effect of the amount and strength of the acid sites of the support on the activity of catalysts with the same elemental composition. We established the nickel‑to‑cobalt as well as phosphorus‑to‑molybdenum ratios in these trimetallic hydrotreating catalysts corresponding to the greatest desulfurization and minimum formation of polycyclic aromatic hydrocarbons in the hydrogenate.