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<p>This study aimed to develop a sustainable method for synthesizing quantum dots (QDs) from crab-derived chitosan waste and evaluate their potential applications in marine environmental monitoring and aquaculture. We employed a microwave-assisted green synthesis protocol where chitosan extracted from local crab processing waste was dissolved in 1% acetic acid, subjected to microwave digestion (180&#xa0;°C, 20&#xa0;min), neutralized to pH 7, and purified through centrifugation, filtration, dialysis, and lyophilization at − 68&#xa0;°C. Comprehensive characterization using multiple analytical techniques (AFM, FTIR, XRD, UV–Vis, photoluminescence) revealed QDs with uniform size distribution (2–4&#xa0;nm), crystalline structure (62% crystallinity index), high quantum yield (46 ± 3%), and exceptional stability in marine environments (87% fluorescence retention in 3.5% NaCl). The QDs demonstrated excellent shelf-life (&gt; 90% activity after 6&#xa0;months at 4&#xa0;°C) and photostability (8% reduction after 6&#xa0;h of continuous UV exposure). Performance testing confirmed their effectiveness for water quality monitoring (detection limits 0.5&#xa0;μM for Hg<sup>2</sup>⁺, 0.8&#xa0;μM for Pb<sup>2</sup>⁺), antifouling applications (78% biofilm reduction), and pollutant remediation (adsorption capacities 187&#xa0;mg/g for methylene blue, 142&#xa0;mg/g for Cu<sup>2</sup>⁺). We conclude that crab-derived chitosan QDs represent a viable circular economy approach to transform seafood industry waste into high-value nanomaterials with significant applications in sustainable aquaculture and marine environmental protection, supporting blue economy innovation through waste valorization while reducing environmental impact.</p>

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Marine waste to blue economy innovation: synthesis and applications of crab-derived chitosan quantum dots for sustainable aquaculture

  • 期刊论文

  • 出版模式：

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  • 发表日期：

    2025年5月14日

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  • Övgü Gencer,
  • Osman Özden

摘要

This study aimed to develop a sustainable method for synthesizing quantum dots (QDs) from crab-derived chitosan waste and evaluate their potential applications in marine environmental monitoring and aquaculture. We employed a microwave-assisted green synthesis protocol where chitosan extracted from local crab processing waste was dissolved in 1% acetic acid, subjected to microwave digestion (180 °C, 20 min), neutralized to pH 7, and purified through centrifugation, filtration, dialysis, and lyophilization at − 68 °C. Comprehensive characterization using multiple analytical techniques (AFM, FTIR, XRD, UV–Vis, photoluminescence) revealed QDs with uniform size distribution (2–4 nm), crystalline structure (62% crystallinity index), high quantum yield (46 ± 3%), and exceptional stability in marine environments (87% fluorescence retention in 3.5% NaCl). The QDs demonstrated excellent shelf-life (> 90% activity after 6 months at 4 °C) and photostability (8% reduction after 6 h of continuous UV exposure). Performance testing confirmed their effectiveness for water quality monitoring (detection limits 0.5 μM for Hg2⁺, 0.8 μM for Pb2⁺), antifouling applications (78% biofilm reduction), and pollutant remediation (adsorption capacities 187 mg/g for methylene blue, 142 mg/g for Cu2⁺). We conclude that crab-derived chitosan QDs represent a viable circular economy approach to transform seafood industry waste into high-value nanomaterials with significant applications in sustainable aquaculture and marine environmental protection, supporting blue economy innovation through waste valorization while reducing environmental impact.