Let A be the path algebra of a quiver of Dynkin type \(\mathbb {A}_n\) . The module category \(mod \,A\) has a combinatorial model as the category of diagonals in a polygon S with \(n+1\) vertices. The recently introduced notion of almost rigid modules is a weakening of the classical notion of rigid modules. The importance of this new notion stems from the fact that maximal almost rigid A-modules are in bijection with the triangulations of the polygon S. In this article, we give a different realization of maximal almost rigid modules. We introduce a non-standard exact structure \(\mathcal {E}_{\diamond }\) on \(mod \,A\) such that the maximal almost rigid A-modules in the usual exact structure are exactly the maximal rigid A-modules in the new exact structure. A maximal rigid module in this setting is the same as a tilting module. Thus the tilting theory relative to the exact structure \(\mathcal {E}_{\diamond }\) translates into a theory of maximal almost rigid modules in the usual exact structure. As an application, we show that with the exact structure \(\mathcal {E}_{\diamond }\) , the module category becomes a 0-Auslander category in the sense of Gorsky, Nakaoka and Palu. We also discuss generalizations to quivers of type \(\mathbb {D}\) and gentle algebras.