Performance and economic feasibility of industrial-scale oxygen production by three-tower VPSA process coupled with partial flushing equalization and natural aspiration/exhaust technology
摘要
A three-tower, nine-step vacuum pressure swing adsorption (VPSA) process coupled with the partial flushing equalization (PFE) and natural aspiration/exhaust (NA/NE) technology was proposed and used for largest industrial-scale 80% oxygen production project in China in this study. The performance of the VPSA system during one whole year showed an obvious seasonal variation, being directly related to the atmosphere humidity and temperature. Correlation analysis between working condition and three performance indicators indicated that feed water and adsorber tower temperature exhibited highly similar linear profiles with respect to O2 recovery and productivity, whereas contrary trend was observed for product flow rate. To achieve the relative constant product flow rate of 56,000 Nm3/h and O2 purity of 83%, two approaches were used in the case of low temperature: decreasing the frequency of blower or increasing the vacuum level. Either way, the obtained higher adsorption/desorption pressure (PH/PL) ratio can indeed increase the O2 purity. Moreover, the typical half-V-shaped profile of energy consumption with increase in adsorber temperature indicated that excessively high or low adsorber tower temperatures led to higher energy consumption. Although higher energy consumption was obtained for lower adsorber temperature of 21–30 ℃ in winter due to the NA process, the competitive energy consumption of 0.28–0.31 kWh/m3 contributed to the economic feasibility of the three-tower, nine-step VPSA process for simultaneous achieving higher O2 yield and lower energy consumption.