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<p>In the field of chemical engineering, achieving deep thiophene removal from coked benzene is a formidable challenge. This, coupled with the limitation of low sulfur capacity, has been major obstacle to the large-scale application of adsorption desulphurisation technology. In this study, Ni-Pt/Al<sub>2</sub>O<sub>3</sub>-CA adsorbent was prepared. The citric acid treated γ-Al<sub>2</sub>O<sub>3</sub> was used as the carrier, and Ni-Pt bimetal as the active component. The relationship between the microstructure and adsorption performance of the adsorbent was investigated by BET, XRD, SEM, TEM, TPR, XPS and Py-FTIR. The results showed that the Ni-Pt/Al<sub>2</sub>O<sub>3</sub>-CA adsorbent could not only reduce the thiophene content in benzene to less than 10 ppb but also had sulfur capacity of 2.73&#xa0;mg S/g compared with the monometallic adsorbent. The adsorption performance of the Ni-Pt/Al<sub>2</sub>O<sub>3</sub>-CA adsorbent was restored to 95% of the initial one after three repetitive experiments. Meanwhile, based on the kinetic modelling results, the quasi-secondary kinetic model fitted the adsorption data of thiophene on Ni-Pt/Al<sub>2</sub>O<sub>3</sub>-CA adsorbent better. And the process of thiophene adsorption was described in depth in the diffusion model.</p>

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Ni-Pt bimetallic adsorbent for deep desulphurization of coked benzene

  • 期刊论文

  • 发表日期：

    2025年3月22日

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  • Jianzheng Jiang,
  • Yunrui Li,
  • Hui Tian,
  • Haisheng Wei,
  • Yao Wang,
  • Xiaoping Chen,
  • Xu Fang

摘要

In the field of chemical engineering, achieving deep thiophene removal from coked benzene is a formidable challenge. This, coupled with the limitation of low sulfur capacity, has been major obstacle to the large-scale application of adsorption desulphurisation technology. In this study, Ni-Pt/Al2O3-CA adsorbent was prepared. The citric acid treated γ-Al2O3 was used as the carrier, and Ni-Pt bimetal as the active component. The relationship between the microstructure and adsorption performance of the adsorbent was investigated by BET, XRD, SEM, TEM, TPR, XPS and Py-FTIR. The results showed that the Ni-Pt/Al2O3-CA adsorbent could not only reduce the thiophene content in benzene to less than 10 ppb but also had sulfur capacity of 2.73 mg S/g compared with the monometallic adsorbent. The adsorption performance of the Ni-Pt/Al2O3-CA adsorbent was restored to 95% of the initial one after three repetitive experiments. Meanwhile, based on the kinetic modelling results, the quasi-secondary kinetic model fitted the adsorption data of thiophene on Ni-Pt/Al2O3-CA adsorbent better. And the process of thiophene adsorption was described in depth in the diffusion model.