Thermal risk assessment of organic sludge solid fuel via experimental evaluation and heat transfer simulation
摘要
Self-heating of organic-sludge solid fuel (OSSF) poses a significant fire hazard during storage. This study investigated its thermal behavior through a combined experimental and computational approach. Three types of pelletized OSSF with different compositions were evaluated using DSC, TG-DTA, and controlled laboratory-scale storage experiments. Sample A exhibited rapid thermal activity, releasing 0.068 W/m3 of heat within 8 days. Sample B, characterized by high oxidizable organic matter (1.05 gCOD/g), reached a warning-level temperature of 51 °C, while Sample C remained below 30 °C, attributed to its lower COD (0.61 gCOD/g) and higher ash content (29%). Heat transfer simulations were conducted using a 3-D transient ANSYS-CFX model, incorporating experimentally measured parameters. The simulations revealed that large-scale storage significantly amplifies thermal risk: Sample A reached 60 °C at the core, indicating potential self-ignition after 10 days; Sample B exceeded 80 °C, substantially higher than observed in laboratory-scale tests. These findings indicate that material properties and storage scale critically influence thermal and self-heating behavior. A predictive framework combining heat-transfer modeling with thermophysical data is proposed to enhance the safe design of OSSF storage. Recommended measures include optimizing OSSF composition and employing real-time thermal monitoring to mitigate thermal-runaway risk in industrial applications.