The synthesis and performance of sea urchin-like manganese cobalt oxide (MnCo2O4) for high-performance supercapacitor electrodes
摘要
Simple hydrothermal method was used to grow sea urchin-like manganese cobalt oxide (MnCo2O4) nanosphere in situ on a nickel foam substrate. TEM images revealed that the sea urchin-like MnCo2O4 nanosphere was assembled from one-dimensional MnCo2O4 nanoneedles, which were about 19 nm and were composed of nanoparticles. Electrochemical tests indicate that the synthesized MnCo2O4 nanosphere exhibited high specific capacitance (2116 F g−1 at 1 A g−1), excellent high current density cycling stability (95% retentions after 8000 cycles at 10 A g−1), and low charge transfer resistance (0.134 Ω). The assembled supercapacitor (SC) device had an energy density of 33.5 Wh kg−1 at a power density of 700 W kg−1. These results indicate that MnCo2O4 sea urchin-like nanosphere is an ideal candidate for high-performance supercapacitor electrodes.