<p>Zinc ferrite (ZnFe<sub>2</sub>O<sub>4</sub>) has attracted considerable attention as a negative electrode material for lithium-ion batteries (LIBs) due to its low cost, environmental friendliness, low toxicity, chemical stability, and especially high theoretical specific capacity (1072 mAh g<sup>−1</sup>). However, its poor electrical conductivity, low rate capability, and large volume change due to the Li<sup>+</sup> uptake and release restrict its practical application. To overcome these limitations, this review has investigated recent advances in improving the electrochemical performance of ZnFe<sub>2</sub>O<sub>4</sub> as a negative electrode material from several aspects: Design and optimization of specific morphologies, ion doping, composite formation with carbon-based materials, and fabrication of heterostructures. This study shows that different methods and synthesis conditions, such as calcination temperature and additives, affect the morphology of ZnFe<sub>2</sub>O<sub>4</sub> nanostructures. The morphology of electrode materials affects various factors such as porosity, diffusion pathway, surface area, and interfacial contact area, and consequently affects the electrochemical performance of LIBs.</p> Graphical abstract <p></p>

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ZnFe2O4 nanostructures as negative electrode materials for lithium-ion batteries: a review

  • Manijeh Shaterian

摘要

Zinc ferrite (ZnFe2O4) has attracted considerable attention as a negative electrode material for lithium-ion batteries (LIBs) due to its low cost, environmental friendliness, low toxicity, chemical stability, and especially high theoretical specific capacity (1072 mAh g−1). However, its poor electrical conductivity, low rate capability, and large volume change due to the Li+ uptake and release restrict its practical application. To overcome these limitations, this review has investigated recent advances in improving the electrochemical performance of ZnFe2O4 as a negative electrode material from several aspects: Design and optimization of specific morphologies, ion doping, composite formation with carbon-based materials, and fabrication of heterostructures. This study shows that different methods and synthesis conditions, such as calcination temperature and additives, affect the morphology of ZnFe2O4 nanostructures. The morphology of electrode materials affects various factors such as porosity, diffusion pathway, surface area, and interfacial contact area, and consequently affects the electrochemical performance of LIBs.

Graphical abstract