We are concerned with the existence of blowing-up solutions to the following boundary value problem \(\begin{aligned} -\Delta u= \lambda V(x) e^u-4\pi N {\varvec{\delta }}_0 \;\hbox { in } B_1,\quad u=0 \;\hbox { on }\partial B_1, \end{aligned}\) where \(B_1\) is the unit ball in \(\mathbb {R}^2\) centered at the origin, V(x) is a positive smooth potential, N is a positive integer ( \(N\ge 1\) ). Here \({\varvec{\delta }}_0\) defines the Dirac measure with pole at 0, and \(\lambda >0\) is a small parameter. We assume that \(N=1\) and, under some suitable assumptions on the derivatives of the potential V at 0, we find a solution which exhibits a non-simple blow-up profile as \(\lambda \rightarrow 0^+\) .