Hydrogen isotope fractionation in olivine-hosted melt inclusions during passive degassing, CO2 flushing, and magma ascent
摘要
Suites of mineral-hosted melt inclusions commonly display variability in their H2O and CO2 concentrations that are challenging to explain by a single process. Recent work has shown that H2O can diffuse rapidly through olivine, allowing olivine-hosted melt inclusions to diffusively equilibrate with an external melt that has a different H2O concentration. This process can cause the concentrations of H2O, and in many cases CO2, in melt inclusions to deviate from isobars and degassing paths. Diffusion of H+ through the olivine lattice can fractionate deuterium (2H or D) from hydrogen, and here we use a discretized diffusive equilibration model to investigate the D+/H+ fractionation associated with passive degassing, CO2 flushing, and magma ascent – three processes that affect the concentration of H2O in the external melt and thereby induce diffusive H2O exchange – on H2O and D+/H+ in olivine-hosted melt inclusions. Our model results show that these three processes lead to distinctly different trends in the H2O concentration and D+/H+ signature of a melt inclusion. However, the timescale of a given process will impact whether the hallmarks of that process are preserved in natural inclusions. While our models focus on olivine-hosted melt inclusions and basanitic melt compositions, the conceptual framework and effects of these processes should apply to any melt inclusion-host crystal system that can be affected by diffusive exchange of hydrogen. Capturing these signatures in datasets is possible, particularly in the case of magma ascent, but it requires high-precision H2O and D+/H+ analyses in a melt inclusion suite that has a wide range of inclusion sizes.