Degassing-driven ascent and explosive eruption of picritic slurries in arc settings
摘要
Although volumetrically minor, ultramafic magmatism in arc settings is globally widespread. The genesis of arc-related ultramafic magmas is hypothesized to require efficient slab dehydration that results in high water concentrations in the hottest portion of the sub-arc mantle wedge where mantle-equilibrated magmas attain picritic compositions. Using the highly variable concentrations of Ca in olivine (Fo89.6−93.5), measured by EPMA, we show that ultramafic volcanic rocks of the Late Triassic Nicola Group in the North American Cordillera record the ascent of crystal-rich picritic slurries (~ 40–60 wt% accumulated olivine + Cr-spinel) driven by limited escape of exsolved H2O ± other volatiles. The picrites record initial crystallization of low-Ca olivine (~ 400 ppm) from an oxidized and water-rich (≥ 8wt.%) near-primary magma containing ~ 19.3 wt% MgO, followed by rapid degassing-driven ascent, during which olivine with high Ca contents (> 2000 ppm) crystallized. The concomitant changes in Mn content and Fe/Mn ratios of olivine and the increasing Fe3+ contents in coexisting Cr-spinel suggest that degassing also resulted in significant oxidation of the melt, possibly through SO2 degassing.