Magnetic-dielectric loss response and tunable magnetic properties influencing microwave absorption in single-phase zinc-doped Cobalt ferrite
摘要
Tunable magnetic material for absorbing microwave was achieved by developing zinc doped cobalt ferrite (Co1−δZnδFe2O4) to reflect its material magnetic property. Mechanical milling was used to make zinc-doped cobalt ferrite from stoichiometric Co3O4, ZnO, and Fe2O3 raw materials. Morphology investigation using SEM demonstrates that particle sizes increase with Zn2+ dopant ion composition. XRD pattern refinement shows all sample compositions are single phase. Peaks indexed to the Fd-3m space group in cubic symmetry resolved satisfactorily. It displayed a peak shift due to the Zn2+ dopant ion, and Raman spectroscopy showed six active Raman vibration modes (2A1g + 3T2g + Eg). The hysteresis curve of CoFe2O4 doped with Zn2+ ions show a decrease in ferrimagnetic behavior with Zn2+ dopant. This decrease in ferrimagnetic behavior is influenced by the cationic distribution of Co2+, Zn2+ and Fe3+ ions in each tetrahedral and octahedral structure. Substitution of Zn2+ ions with a composition of 0 ≤ δ ≤ 1 obtained saturation magnetization through the equation M = -73.143δ2 − 7.2571δ + 85.757. While the coercivity field follows the relationship y = -1440δ3 + 2668.6δ2 − 1668.6δ + 438.57. Permittivity and permeability decrease with increasing concentration of Zn2+ dopant ions. Two microwave absorption peaks in the X band indicate satisfactory functionality as a microwave absorber. The magnitude of RLmax can be obtained through the relationship y = -29.867δ3 + 49.6δ2 − 22.933δ − 12.1.