<p> Injection-Dependent Lifetime Spectroscopy (IDLS) is used within this study for a parameterisation of interstitial iron Fe<sub>i</sub> in p type Czochralski &lt;100&gt; silicon wafers. The first step is dedicated to study the presence of iron contamination using the crossover method for Fe<sub>i</sub> and Iron-Bore pairs (Fe-B) dissociation, then the IDLS supported by the Defect Parameter Solution Surface (DPSS) are performed for the determination of capture coefficient σ<sub>n</sub>/σ<sub>p</sub> (σ<sub>n</sub>, σ<sub>p</sub> are the capture cross section for electrons and holes respectively) and the energy level in the band gap of Fe<sub>i</sub> related defect (E<sub>t</sub>). The obtained parameters, σ<sub>n</sub>/σ<sub>p</sub>= 21 and E<sub>t</sub>= E<sub>V</sub>+0.38 eV, where E<sub>v</sub> is the valence band energy, were used to fit the experimental Shockley–Read–Hall (SRH) lifetime provided by Quasi-Steady-State PhotoConductance measurement (QSSPC) to assess σ<sub>n</sub> and σ<sub>p</sub>. The objective of the second part of this work was to demonstrate the relationship between σ<sub>n</sub> and the concentration of [Fe<sub>i</sub>]. It is important to note that the electron-capture cross-section of Fe<sub>i</sub> has been determined less accurately in the literature compared to the hole-capture cross-section and the energy level within the band gap E<sub>t</sub>. To validate the relationship between σ<sub>n</sub> and the concentration of Fe<sub>i</sub>, we assumed a value of 7×10<sup>-17</sup> cm<sup>2</sup> for σ<sub>p</sub> and a value of E<sub>V</sub>+0.38 eV for energy level of trap E<sub>t</sub>, as reported in the literature. Subsequently, the value of σ<sub>n</sub> was determined through the application of the equation K = σ<sub>n</sub>/σ<sub>p</sub>, which yielded a result of 21. The resulting parameters were then employed in the fitting of experimental data of the Shockley–Read–Hall lifetime (τ<sub>srh</sub>) versus injection level (∆n) [cm<sup>-3</sup>].</p>

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Parameterisation of interstitial iron-related defects in silicon wafers using injection-dependent lifetime spectroscopy

  • Mohamed MaoudJ,
  • Djoudi Bouhafs

摘要

Injection-Dependent Lifetime Spectroscopy (IDLS) is used within this study for a parameterisation of interstitial iron Fei in p type Czochralski <100> silicon wafers. The first step is dedicated to study the presence of iron contamination using the crossover method for Fei and Iron-Bore pairs (Fe-B) dissociation, then the IDLS supported by the Defect Parameter Solution Surface (DPSS) are performed for the determination of capture coefficient σnpn, σp are the capture cross section for electrons and holes respectively) and the energy level in the band gap of Fei related defect (Et). The obtained parameters, σnp= 21 and Et= EV+0.38 eV, where Ev is the valence band energy, were used to fit the experimental Shockley–Read–Hall (SRH) lifetime provided by Quasi-Steady-State PhotoConductance measurement (QSSPC) to assess σn and σp. The objective of the second part of this work was to demonstrate the relationship between σn and the concentration of [Fei]. It is important to note that the electron-capture cross-section of Fei has been determined less accurately in the literature compared to the hole-capture cross-section and the energy level within the band gap Et. To validate the relationship between σn and the concentration of Fei, we assumed a value of 7×10-17 cm2 for σp and a value of EV+0.38 eV for energy level of trap Et, as reported in the literature. Subsequently, the value of σn was determined through the application of the equation K = σnp, which yielded a result of 21. The resulting parameters were then employed in the fitting of experimental data of the Shockley–Read–Hall lifetime (τsrh) versus injection level (∆n) [cm-3].