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Semiconducting BaS3:La2S3:DyS1.8 multinary metal chalcogenide hetero-system prepared via single source precursor route: expounding energy storage potential

  • Shaan Bibi Jaffri,
  • Khuram Shahzad Ahmad,
  • Jehad S. Al-Hawadi,
  • Niharika Maley,
  • Ram K. Gupta,
  • Ghulam Abbas Ashraf,
  • Aboud Ahmed Awadh Bahajjaj

摘要

The current study is concerned with understanding the synthesis and application of the diversified BaS3:La2S3:Dy1.8 dithiocarbamate sulphide by the single source precursor (SSP) approach. Analytical approaches were used to evaluate the optical, crystalline, vibrational crosslinking, morphological, and thermal properties of BaS3:La2S3:Dy1.8 chalcogenide. The synthesized chalcogenide has an average crystallite size of 16.35 nm and mixed phases, with a direct band gap energy of 3.9 eV. The study of functional groups revealed the presence of metal sulphide bonds. In terms of morphology, BaS3:La2S3:Dy1.8 chalcogenide has an uneven shape with a small amount of aggregation. The electrochemical charge storage behavior of BaS3:La2S3:Dy1.8 was studied using a nickel foam electrode. The trichalcogenide-decorated electrode exhibited charge-storing behavior, with a specific capacitance of 723 F g− 1 determined by cyclic voltammetry. The electrode has a specific power density of 11,166 W kg− 1 and a low series resistance of 0.9 Ω, as shown by impedance measurements.