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Potential environment effect on ultrahigh resolution Sr/Ca of giant clam shells from South China Sea

  • Chengcheng Liu,
  • Hong Yan,
  • Liqiang Zhao,
  • Nanyu Zhao,
  • Fan Luo,
  • Hanfeng Wen,
  • Haotian Yang,
  • Wei Yang,
  • Jialong Hao,
  • Chengde Liang,
  • Kentaro Tanaka,
  • Naoko Murakami-Sugihara,
  • Kotaro Shirai,
  • Naoto Takahata,
  • John Dodson,
  • Bernd R. Schöne

摘要

The hourly to monthly resolution Sr/Ca profiles of modern juvenile giant clam (Tridacna spp.) shells from the northern South China Sea were obtained using ICP-OES, LA-ICP-MS and NanoSIMS. The results showed the variability of Sr/Ca profiles determined by different analytical methods were consistent on monthly time scale. The hourly resolved Sr/Ca determined by NanoSIMS showed pronounced daily cycles which may be associated with the diurnal cycle of the physiology, environment and/or weather condition. By comparison of daily resolution Sr/Ca and contemporaneous instrumental environment data, no robust link was observed between environmental parameters and juvenile Tridacna Sr/Ca, and only weak correlation was found between daily outgoing longwave radiation (OLR) (r =  − 0.167, p < 0.01) and Sr/Ca. However, the effective solar radiation cannot explain the variability of nightly Sr/Ca, and some other factors are more likely to influence the Sr/Ca of juvenile Tridacna. Moreover, no consistent correlation was observed between Sr/Ca and growth rate of Tridacna. The mechanism of juvenile Tridacna Sr/Ca is still mysterious, conducting artificial culture experiments seems the best way to unravel the mechanisms behind Sr2+ incorporation into Tridacna shells.