We prove a parabolic analogue of Wolff’s inequality adapted to the intrinsic scaling \(\delta _c(x,t)=(cx,c^2t)\) and formulated in terms of time-backward parabolic dyadic rectangles. As a consequence, we obtain equivalent characterizations of parabolic \((\alpha ,q)\) -thinness in this geometric setting and establish the associated Kellogg and Choquet properties. We further use the notion of \((\alpha ,2)\) -thinness defined in terms of fractional heat balls and prove that the sets of irregular boundary points \(z_0\in \partial \Omega \) for the heat operator \(\partial _t-\Delta \) and for the degenerate operator \(\mathscr {L}a=\partial _t(|y|^a\cdot )-\operatorname {div}(|y|^a\nabla \cdot )\) in \(\Omega \subset \mathbb {R}^{d+1}\) are negligible with respect to the thermal capacity \(\text {cap} ^{\mathscr {T}}\) and the parabolic Bessel capacity \(C_{\alpha ,2}\) , respectively.