Let G be a classical group, i.e., either isomorphic to \(\textrm{GL}_n\) or the group of isometries of a non-degenerate symmetric or anti-symmetric bilinear form on a vector space over an algebraically closed field k of characteristic zero. Let \(\theta \) be an involution on G and let \(G_0\) be the fixed point subgroup \(G^\theta \) . Let \(\mathfrak {g}\) and \(\mathfrak {g}_0\) be the Lie algebras of G and \(G_0\) respectively. Let \(\tau \) be the automorphism on \(\mathfrak {g}\) induced by \(\theta \) . Let \(\mathfrak {g}_1\) be the \(-1\) eigenspace of \(\tau \) . For \(d \ge 2\) , let \(\mathfrak {C}^d(\mathfrak {g}_1)\) be the d-th commuting scheme associated with the symmetric pair \((\mathfrak g, \mathfrak g_0)\) . In this article, we study the reducedness of the quotient scheme \(\mathfrak {C}^d(\mathfrak {g}_1)//{G_0}\) via the Chevalley restriction map. As a part of the proof, we describe a generating set for the algebra \(k[\mathfrak {g}_1^d]^{G_0}\) , which is of independent interest.