In this paper, we investigate the global existence of classical solution to the following two-species chemotaxis-competition model with weak singular sensitivity and Lotka-Volterra competitive kinetics 0.1 \(\begin{aligned} {\left\{ \begin{array}{ll} u_t=\Delta u-\chi _1\nabla \cdot (\frac{u}{w^\alpha }\nabla w)+u(a_1-b_1u-c_1v), & t>0,~x\in \Omega ,\\ v_t=\Delta v-\chi _2\nabla \cdot (\frac{v}{w^\beta }\nabla w)+v(a_2-b_2v-c_2u), & t>0,~x\in \Omega ,\\ \tau w_t=\Delta w- w+ u+ v, & t>0,~x\in \Omega ,\\ \frac{\partial u}{\partial \nu }=\frac{\partial v}{\partial \nu }=\frac{\partial w}{\partial \nu }=0, & t>0,~x\in \partial \Omega ,\\ u(0,x)=u_0(x),~~v(0,x)=v_0(x),~~\tau w(0,x)=\tau w_0(x), & x\in \Omega , \end{array}\right. } \end{aligned}\) where \(\Omega \subset \mathbb {R}^N(N\ge 1)\) is a bounded smooth domain, \(\tau \in \{0,1\}\) and the parameters \(\alpha ,\beta ,\chi _i,a_i,b_i,c_i(i=1,2)\) are all positive constants. When \(\tau =0\) and \(\alpha =\beta \) , we prove that there exist \(M^*>0\) and \(C^*>0,\) if \(\begin{aligned} \alpha \in (0,1),~~~\min \{b_1,b_2,c_1,c_2\}>\chi M^*(N,\alpha ,\chi ),~~\text {when}~\chi _1=\chi _2=:\chi , \end{aligned}\) or \(\begin{aligned} \begin{aligned} \alpha \in \left( \frac{1}{2},1\right) ,~\min \{b_1,b_2&,c_1,c_2\}>\min \{\chi _1M^*(N,\alpha ,2\chi _1)+(\chi _2-\chi _1)^2C^*(N,\alpha ,\chi _2,\chi _1),\\&\chi _2M^*(N,\alpha ,2\chi _2)+(\chi _1-\chi _2)^2C^*(N,\alpha ,\chi _1,\chi _2)\},~\text {when}~\chi _1\ne \chi _2 \end{aligned} \end{aligned}\) then for any given nonnegative initial data \(u_0, v_0\in C^0(\overline{\Omega }),~\text {and}~\int _{\Omega }u_0(x)+v_0(x){\text {d}}x>0,\) the problem (0.1) possesses a unique globally defined classical solution. Moreover, the solutions are shown to be uniformly bounded of solution under the additional assumption \(\begin{aligned}\alpha \in \left( \frac{1}{2},\frac{1}{2}+\frac{1}{N}\right) ~~\text {with}~~N\ge 2. \end{aligned}\) When \(\tau =1\) and \(\alpha ,\beta >0\) , we prove that if \(\min \{b_1,b_2,c_1,c_2\}\) is sufficiently large, then for any given nonnegative initial data \(u_0, v_0\in C^0(\overline{\Omega }),~\text {and}~0<w_0(x)\in W^{1,\infty }(\Omega ),\) the problem (0.1) possesses a unique global classical solution.