<p>We study tree-level scattering processes of arbitrary string states using the DDF formalism and suitable coherent vertex operators. We obtain new exact compact formulae for heavy-heavy-light-light scattering amplitudes in open or closed bosonic string theories, and derive explicit exact expressions for the absorption cross-sections, and corresponding emission rates, of highly excited string states using the optical theorem and time reversal symmetry. We show that these expressions are independent of the microscopic structure of the excited string states without averaging. For the absorption of massless modes in open string theory, in particular, we find a constant, frequency-independent cross-section. In contrast, the corresponding cross-section for the absorption of massless modes by excited closed strings depends linearly on the frequency, implying a non-trivial grey-body factor. In both cases, at energies below the scale set by the mass of the highly excited strings, we find emission rates with a Boltzmann factor at Hagedorn temperature.</p>